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Cook provided the voice for Chelsea Cunningham on the Kids' WB animated series Batman Beyond and in the animated film Batman Beyond: Return of the Joker.
In 1999, Cook starred her breakout role in the sleeper hit film She's All That, a romantic comedy that so far is the most financially successful film of her career.
“We got married incredibly fast,” the actress, 33, told PEOPLE from the set of her TNT crime-drama, .
“We got engaged after dating for maybe five months and we got married a couple of months after that.
Cook first gained national attention in 1998, when she was featured in the famous This Is Your Brain on Drugs PSA television advertisement, in which she proceeds to destroy a kitchen with a frying pan as she lists the important things in life that heroin harms.
In 2011, she was selected by the Obama administration as a Champion of Change for Arts Education.